Abstract Electrochemical CO2 reduction to fuels necessitates multiple steps of electron and proton transer.

Abstract Three-dimensional (3D) covalent organic frameworks (COFs) hold significant promise for a variety of appli...

Abstract Developing porous materials with ultrahigh surface areas for gas storage (for example, methane) is attractive but challenging.

Current COF crystallization is trial/error & harsh. Using micelles to separate monomers enables controlled growth, yielding gram-scale single-crystal (5 3D, 1 2D) with >92% yields in water.